Difference between revisions of "Iron chromate"

From CAMEO
Jump to navigation Jump to search
 
(2 intermediate revisions by the same user not shown)
Line 2: Line 2:
 
== Description ==
 
== Description ==
  
A yellow powder occasionally used as a pigment called siderin yellow. Iron chromate is precipitated from a solution of a chromate salt, such as [[potassium dichromate]] by the addition of [[ferric chloride]]. The pure pigment is bright yellow, but some residual impurities, such as [[ferric oxide|iron oxide]], may result in a dull orange pigment color. Siderin yellow is compatible with all paint binders. It has also been used as a gray or brown ceramic glaze and as a colorant in glass and enamel.
+
A yellow powder occasionally used as a pigment called siderin yellow. Iron chromate is precipitated from a solution of a chromate salt, such as [[potassium dichromate]] by the addition of [[ferric chloride]]. The pure pigment is bright yellow, but some residual impurities, such as [[ferric oxide|iron oxide]], may result in a dull orange pigment color. Siderin yellow is compatible with all paint binders. Iron chromate produces a gray ceramic glaze when used in concentrations of 0.5-2.0%, while it produces a brown glaze color when mixed with zinc.  It has also been used as as a colorant in glass and enamel.
  
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
Line 34: Line 34:
  
 
* H. Kuhn, M.Curran, "Chrome Yellow and Other Chromate Pigments", ''Artists Pigments'', Volume 1, R. Feller (ed.), Cambridge University Press: Cambridge, 1986.
 
* H. Kuhn, M.Curran, "Chrome Yellow and Other Chromate Pigments", ''Artists Pigments'', Volume 1, R. Feller (ed.), Cambridge University Press: Cambridge, 1986.
 
+
* Robert Fournier, ''Illustrated Dictionary of Practical Pottery'' Chilton Book Company, Radnor, PA, 1992.
 
* Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993
 
* Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993
 
 
* Michael McCann, ''Artist Beware'', Watson-Guptill Publications, New York City, 1979
 
* Michael McCann, ''Artist Beware'', Watson-Guptill Publications, New York City, 1979
 
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983
  

Latest revision as of 14:12, 6 July 2024

Chrome yellow background
MFA# 40.777

Description

A yellow powder occasionally used as a pigment called siderin yellow. Iron chromate is precipitated from a solution of a chromate salt, such as Potassium dichromate by the addition of Ferric chloride. The pure pigment is bright yellow, but some residual impurities, such as iron oxide, may result in a dull orange pigment color. Siderin yellow is compatible with all paint binders. Iron chromate produces a gray ceramic glaze when used in concentrations of 0.5-2.0%, while it produces a brown glaze color when mixed with zinc. It has also been used as as a colorant in glass and enamel.

Synonyms and Related Terms

siderin yellow; Pigment Yellow 45; CI 77505; chromate de fer (Fr.); cromato de ferro (Port.); chromate of iron; ferric chromate

Risks

  • Human carcinogen.
  • Skin contact may cause allergies. Acute ingestion may cause fatal chromium poisoning.
  • Chronic inhalation may cause lung cancer and respiratory irritation.
  • ThermoFisher: SDS

Physical and Chemical Properties

Soluble in acids. Insoluble in water, and ethanol.

Composition Fe2(CrO4)3
CAS 10294-52-7
Molecular Weight mol. wt. = 459.73

Resources and Citations

  • H. Kuhn, M.Curran, "Chrome Yellow and Other Chromate Pigments", Artists Pigments, Volume 1, R. Feller (ed.), Cambridge University Press: Cambridge, 1986.
  • Robert Fournier, Illustrated Dictionary of Practical Pottery Chilton Book Company, Radnor, PA, 1992.
  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • Michael McCann, Artist Beware, Watson-Guptill Publications, New York City, 1979
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983