Chrysophanic acid

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Description

A natural yellow anthraquinone dyestuff found in the roots of rhubarb (Rheum rhabarbarum) plants and in a yellow colored lichen, Xanthoria parietina, in the form of parietin. Chrysophanic acid is extracted from the ground plant in an alkaline solution. The yellow colorant precipitates when the solution is neutralized with an acid. When used as a dye, it can produce shades of yellow, gold, and orange, with potential for pinks using modifiers. Alum can improve lightfastness and brighten colors.

Chemical structure

Chrysophanic acid.jpg

Synonyms and Related Terms

1,8-dihydroxy-3-methylanthraquinone; Natural Yellow 23; CI 75400; chrysophanol; 3-methylchrysazin; 1,8-dihydroxy-3-methyl-9,10-anthracenedione; rhenic acid; acido crisofanico (It.); Turkey rhubarb; Xanthoria parietina;

Risks

  • Contact may cause irritation.
  • Ingestion may cause nausea and vomiting.
  • Fisher Scientific: MSDS

Physical and Chemical Properties

  • Soluble in ethanol, benzene, chloroform, ether, acetone, acids, alkalis. Insoluble in water.
  • Absorption max. = 226, 256, 278, 288, 436 nm.
  • Composition = C15H10O4
  • CAS = 481-74-3
  • Melting Point = 196 C
  • Molecular Weight = 254.24

Resources and Citations

  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 2318
  • F. Crace-Calvert, Dyeing and Calico Printing, Palmer & Howe, London, 1876 Comment: pp. 296 and 298
  • Sigma Dyes, Stains and Natural Pigments, Infrared Library, Nicolet, 1991-1995 Comment: OMNIC: formula= C15H10O4, CAS= 481-74-3
  • Wikipedia: Chrysophanol Accessed April 2026