Trioxane

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Description

White, crystalline solid with a formaldehyde odor. Trioxane is a trimer of anhydrous formaldehyde in a linked ring structure. It is used as a tanning agent and as a source for formaldehyde. Pellets of trioxane are used as a solid fuel in portable heating units.

Synonyms and Related Terms

sym-trioxane; 1,3,5-trioxane; 1,3,5-trioxacyclohexane; metaformaldehyde; trioxymethylene; triformal

Chemical structure

Trioxane.jpg


Other Properties

Soluble in water and polar organic solvents. Insoluble in aliphatic hydrocarbons. Decomposes with acids to produce formaldehyde.

Composition (HCHO)3
CAS 110-88-3
Melting Point 62
Density 1.17
Molecular Weight mol. wt. = 90.08
Boiling Point 115

Hazards and Safety

Fire risk. Ignites readily. Burns with an odorless hot flame.

Fisher Scientific: MSDS

Authority

  • G.S.Brady, G.S.Brady, Materials Handbook, McGraw-Hill Book Co., New York, 1971 Comment: p. 23
  • Richard S. Lewis, Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • Van Nostrand's Scientific Encyclopedia, Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 9863

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