Diarylide dye

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Description

A class of synthetic yellow, orange, and red organic colorants. Diarylide dyes are insoluble direct azo dyes that were first synthesized from benzidine in 1911. They were not widely used until the 1930s. Diarylide yellows have good tinting strength, opacity and solvent resistance. They have fair to good lightfastness and are primarily used in printing inks, plastic, rubbers, as well as architectural and artists paints.

See also Arylide.

Synonyms and Related Terms

diarylide dyes; disazo dye; benzidine yellow; Pigment Yellow 12; Pigment Orange 13; Pigment Red 41; Pigment Yellow 83; benzidine orange

FTIR PY12(MFA)

PY12 Diarylide yellow.TIF

FTIR PY13(MFA)

PY013 sun diarylide AAMX yellow rs 275-1149.TIF

FTIR PY14(MFA)

PY14 Diarylide yellow (magruder ya1161-lu).PNG

FTIR PY17(MFA)

PY17 Sunbright Yellow 17.PNG

FTIR PY83(MFA)

PY083 diarylide AADMC yellow 275-0570.TIF

FTIR PY127(MFA)

PY127 Diarylide Yellow.PNG

FTIR PO34(MFA)

PO034 sun diarylide tolyl orange 282-0034.TIF

Comparisons

Pigment number Manufacture Pigment name Manufacture CI number Comments
PY012 unknown diarylide yellow unknown
PY013 Sun diarylide AAMX yellow_rs 275-1149
PY014 Sun diarylide AAOT yellow 274-1744 FTIR spectra appear the same for all PY014
PY014 Magruder diarylide yellow AAoT t-p lumps ya1161-lu FTIR spectra appear the same for all PY014
PY014 Magruder diarylide yellow AAoT s_o ya1283-dc FTIR spectra appear the same for all PY014
PY017 Sun diarylide AAOA yellow 275-0023
PY083 Magruder diarylide yellow yr1300-dc FTIR spectra are the same for Sun and Magruder PY083
PY083 Sun diarylide AADMC yellow 275-0570 FTIR spectra are the same for Sun and Magruder PY083
PY127 unknown diarylide yellow unknown
PO034 Sun diarylide tolyl orange 282-0034

Physical and Chemical Properties

Resistant to alkalis and heat.

Risks

Highly toxic. Suspected carcinogen and teratogen. May cause bladder cancer. .

Resources and Citations

  • Michael McCann, Artist Beware, Watson-Guptill Publications, New York City, 1979
  • Monona Rossol, The Artist's Complete Health and Safety Guide, Allworth Press, New York, 1994
  • Thomas B. Brill, Light Its Interaction with Art and Antiquities, Plenum Press, New York City, 1980
  • B. Berrie, S.Q. Lomax, 'Azo Pigments: Their History, Synthesis, Properties and Use in Artists' Materials', Studies in the History of Art , National Gallery of Art, Washington DC, No. 57, 1997