Difference between revisions of "Glycerol"

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A transparent, colorless, viscous liquid that is hygroscopic and has a sweet taste. Glycerol,  first isolated in 1779 by Scheele, is a byproduct from the saponification of fats and oils. It is used in the production of alkyd resins, ester gums and dynamite. The thick, neutral liquid is also used as an emulsifier/plasticizer in printing inks, watercolor and gouache paints, glues, cements, and regenerated cellulose ([[viscose rayon|rayon]], [[cellophane]]). In some formulations, glycerol is substituted with [[sorbitol]], or [[corn syrup]]. The term glycerin is used for commercial materials containing more than 95 percent glycerol.
 
A transparent, colorless, viscous liquid that is hygroscopic and has a sweet taste. Glycerol,  first isolated in 1779 by Scheele, is a byproduct from the saponification of fats and oils. It is used in the production of alkyd resins, ester gums and dynamite. The thick, neutral liquid is also used as an emulsifier/plasticizer in printing inks, watercolor and gouache paints, glues, cements, and regenerated cellulose ([[viscose rayon|rayon]], [[cellophane]]). In some formulations, glycerol is substituted with [[sorbitol]], or [[corn syrup]]. The term glycerin is used for commercial materials containing more than 95 percent glycerol.
 
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[[[SliderGallery rightalign|aaiGLYCERIN.jpg~FTIR|glycerol.jpg~Chemical structure]]]
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
  
 
glycerin; glycerine; glycol alcohol; 1,2,3-propanetriol; trihydroxypropane; sweet oil; glyceryl alcohol
 
glycerin; glycerine; glycol alcohol; 1,2,3-propanetriol; trihydroxypropane; sweet oil; glyceryl alcohol
  
[[[SliderGallery rightalign|aaiGLYCERIN.jpg~FTIR|glycerol.jpg~Chemical structure]]]
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== Risks ==
 +
 
 +
* Combustible. May explode if mixed with strong oxidizing agents such as chromium trioxide, potassium chlorate or potassium permanganate. 
 +
* ThermoFisher: [https://www.fishersci.com/store/msds?partNumber=AA4388330&productDescription=GLYCEROL+MONOSTEARATE+PFD+250G&vendorId=VN00024248&countryCode=US&language=en SDS]
  
== Other Properties ==
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== Physical and Chemical Properties ==
  
 
Miscible with water, ethanol. Insoluble in ether, benzene and chlorinated hydrocarbons.
 
Miscible with water, ethanol. Insoluble in ether, benzene and chlorinated hydrocarbons.
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|-
 
|-
 
! scope="row"| Melting Point
 
! scope="row"| Melting Point
| 17.8
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| 17.8 C
 
|-
 
|-
 
! scope="row"| Density
 
! scope="row"| Density
| 1.2653
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| 1.2653 g/ml
 
|-
 
|-
 
! scope="row"| Molecular Weight
 
! scope="row"| Molecular Weight
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|-
 
|-
 
! scope="row"| Boiling Point
 
! scope="row"| Boiling Point
| 290
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| 290 C
 
|}
 
|}
 
== Hazards and Safety ==
 
 
Combustible. May explode if mixed with strong oxidizing agents such as chromium trioxide, potassium chlorate or potassium permanganate. 
 
 
LINK: [http://www.cdc.gov/niosh/ipcsneng/neng0624.html International Chemical Safety Card]
 
  
 
== Comparisons ==
 
== Comparisons ==
  
[[media:download_file_130.pdf|Properties of Common Solvents]]
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[[media:download_file_138.pdf|Properties of Common Solvents]]
 
 
 
 
  
== Authority ==
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== Resources and Citations ==
  
* ''Encyclopedia Britannica'', http://www.britannica.com  Comment: Glycerol. Retrieved June 1, 2003, from Encyclopædia Britannica Premium Service.
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* ''Encyclopedia Britannica'', http://www.britannica.com  Comment: Glycerol. Retrieved June 1, 2003.
  
 
* R. J. Gettens, G.L. Stout, ''Painting Materials, A Short Encyclopaedia'', Dover Publications, New York, 1966
 
* R. J. Gettens, G.L. Stout, ''Painting Materials, A Short Encyclopaedia'', Dover Publications, New York, 1966
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* S.R.Trotman, E.R. Trotman, ''Textile Analysis'', J.B. Lippincott Company, Philadelphia, 1932
 
* S.R.Trotman, E.R. Trotman, ''Textile Analysis'', J.B. Lippincott Company, Philadelphia, 1932
  
* Website address 1  Comment: conservation termlist : www.hants.org.uk/museums
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* Conservation termlist : www.hants.org.uk/museums
  
  
  
 
[[Category:Materials database]]
 
[[Category:Materials database]]

Revision as of 08:55, 30 August 2022

Description

A transparent, colorless, viscous liquid that is hygroscopic and has a sweet taste. Glycerol, first isolated in 1779 by Scheele, is a byproduct from the saponification of fats and oils. It is used in the production of alkyd resins, ester gums and dynamite. The thick, neutral liquid is also used as an emulsifier/plasticizer in printing inks, watercolor and gouache paints, glues, cements, and regenerated cellulose (rayon, Cellophane). In some formulations, glycerol is substituted with Sorbitol, or Corn syrup. The term glycerin is used for commercial materials containing more than 95 percent glycerol.

FTIR

AaiGLYCERIN.jpg

Chemical structure

Glycerol.jpg

Synonyms and Related Terms

glycerin; glycerine; glycol alcohol; 1,2,3-propanetriol; trihydroxypropane; sweet oil; glyceryl alcohol

Risks

  • Combustible. May explode if mixed with strong oxidizing agents such as chromium trioxide, potassium chlorate or potassium permanganate.
  • ThermoFisher: SDS

Physical and Chemical Properties

Miscible with water, ethanol. Insoluble in ether, benzene and chlorinated hydrocarbons.

Composition C3H8O3
CAS 56-81-5
Melting Point 17.8 C
Density 1.2653 g/ml
Molecular Weight mol. wt. = 92.1
Boiling Point 290 C

Comparisons

Properties of Common Solvents

Resources and Citations

  • R. J. Gettens, G.L. Stout, Painting Materials, A Short Encyclopaedia, Dover Publications, New York, 1966
  • Ralph Mayer, A Dictionary of Art Terms and Techniques, Harper and Row Publishers, New York, 1969 (also 1945 printing)
  • Matt Roberts, Don Etherington, Bookbinding and the Conservation of Books: a Dictionary of Descriptive Terminology, U.S. Government Printing Office, Washington DC, 1982
  • Reed Kay, The Painter's Guide To Studio Methods and Materials, Prentice-Hall, Inc., Englewood Cliffs, NJ, 1983
  • S.R.Trotman, E.R. Trotman, Textile Analysis, J.B. Lippincott Company, Philadelphia, 1932
  • Conservation termlist : www.hants.org.uk/museums

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