Difference between revisions of "Paratoluidine"

From CAMEO
Jump to navigation Jump to search
(username removed)
 
(2 intermediate revisions by one other user not shown)
Line 1: Line 1:
 
== Description ==
 
== Description ==
  
Transparent colorless crystals prepared by treating nitrotoluene with [http://cameo.mfa.org/materials/fullrecord.asp?name=acetic%20acid acetic acid] in the presence of [http://cameo.mfa.org/materials/fullrecord.asp?name=iron iron]. Paratoluidine is used in the manufacture of some synthetic organic red colorants. Paratoluidine reds are sometimes used in inks but are not used as an artist colors because they bleed and fade with time.
+
Transparent colorless crystals prepared by treating nitrotoluene with [[acetic%20acid|acetic acid]] in the presence of [[iron|iron]]. Paratoluidine is used in the manufacture of some synthetic organic red colorants. Paratoluidine reds are sometimes used in inks but are not used as an artist colors because they bleed and fade with time.
 
+
[[[SliderGallery rightalign|paratoluidine.jpg~Chemical structure]]]
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
  
 
p-toluidine; 4-aminotoluene; 4-amino-1-methylbenzene; p-methylaniline
 
p-toluidine; 4-aminotoluene; 4-amino-1-methylbenzene; p-methylaniline
  
[[[SliderGallery rightalign|paratoluidine.jpg~Chemical structure]]]
+
== Risks ==
 +
 
 +
* Toxic by ingestion, inhalation and skin absorption.   
 +
* Combustible. Flash point = 86C (188F) 
 +
* NIH: [https://pubchem.ncbi.nlm.nih.gov/compound/p-Toluidine Compound summary]
  
== Other Properties ==
+
== Physical and Chemical Properties ==
  
 
Soluble in alcohols, ether, acetone, carbon disulfide, oils, dilute acids.  Slightly soluble in water.   
 
Soluble in alcohols, ether, acetone, carbon disulfide, oils, dilute acids.  Slightly soluble in water.   
Line 24: Line 28:
 
|-
 
|-
 
! scope="row"| Melting Point
 
! scope="row"| Melting Point
| 44-45
+
| 44-45 C
 
|-
 
|-
 
! scope="row"| Density
 
! scope="row"| Density
| 1.046
+
| 1.046 g/ml
 
|-
 
|-
 
! scope="row"| Molecular Weight
 
! scope="row"| Molecular Weight
Line 33: Line 37:
 
|-
 
|-
 
! scope="row"| Boiling Point
 
! scope="row"| Boiling Point
| 200-201
+
| 200-201 C
 
|}
 
|}
  
== Hazards and Safety ==
+
==Resources and Citations==
 
 
Toxic by ingestion, inhalation and skin absorption.   
 
 
 
Combustible. Flash point = 86C (188F) 
 
 
 
[http://www.cdc.gov/niosh/ipcsneng/neng0343.html International Chemical Safety Card]
 
 
 
== Authority ==
 
  
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 9396
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 9396
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 9366
 
  
 
* F. Crace-Calvert, ''Dyeing and Calico Printing'', Palmer & Howe, London, 1876
 
* F. Crace-Calvert, ''Dyeing and Calico Printing'', Palmer & Howe, London, 1876

Latest revision as of 14:36, 17 October 2022

Description

Transparent colorless crystals prepared by treating nitrotoluene with Acetic acid in the presence of Iron. Paratoluidine is used in the manufacture of some synthetic organic red colorants. Paratoluidine reds are sometimes used in inks but are not used as an artist colors because they bleed and fade with time.

Chemical structure

Paratoluidine.jpg

Synonyms and Related Terms

p-toluidine; 4-aminotoluene; 4-amino-1-methylbenzene; p-methylaniline

Risks

  • Toxic by ingestion, inhalation and skin absorption.
  • Combustible. Flash point = 86C (188F)
  • NIH: Compound summary

Physical and Chemical Properties

Soluble in alcohols, ether, acetone, carbon disulfide, oils, dilute acids. Slightly soluble in water.

Darkens on exposure to air.

Composition C6H4CH3NH2
CAS 106-49-0
Melting Point 44-45 C
Density 1.046 g/ml
Molecular Weight mol. wt. = 107.2
Boiling Point 200-201 C

Resources and Citations

  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 9396
  • F. Crace-Calvert, Dyeing and Calico Printing, Palmer & Howe, London, 1876