Barium sulfate

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barite

Contents

Description

A white pigment obtained naturally from the mineral barite. Barium sulfate was developed as an artist pigment in the late 18th century as a nonpoisonous alternative to lead white. Barium sulfate is an inert, transparent pigment that is often used as a filler or as a base for lake pigments. In recent years, it has also been used as a filler and extender in paper, wallpaper, linoleum, oilcloth, rubber, plastics, flannel, and shoddy cloth. Barium sulfate can also be made artificially by a process discovered in late nineteenth century. Artificially prepared barium sulfate is called blanc fixe. In order to increase its opacity, barium sulfate is mixed with zinc sulfide, to form lithopone. Permalba is an opaque version of barium sulfate which is sold as a permanent artist pigment.

Barium sulfate

Synonyms and Related Terms

baryte; Pigment White 22 (natural); Pigment White 21 (synthetic); CI 77120 (both); barium sulphate (Br.); blanc fixe (Fr.); basofor; Baryt (Deut.); Schwerspat (Deut.); Barytweiss (Deut.); solfato di bario (It.); bianco fisso (It.); blanco fijo (Esp.); sulfate de baryum (Fr.); baritis (Gr.); bariet (Ned.); sulfato de bário (Port.); artificial barite; baratine; baryta white; barium white; permanent white; Permalba; heavy spar; Bologna white; Bolognian spar; Tyrol white; cauk

Raman

BarytesUCL.jpg

Raman

Bariteitaly1.jpg

FTIR

MFA- Barium sulfate.jpg

XRD

PIG495.jpg

XRF

Slide19 F525.PNG


Other Properties

Chemically resistant to acids, alkalis and corrosive gases.

Particle size = 0.11-0.54 microns. Low birefringence.

Isotropic but under cross polars the particles may appear to twinkle.

Composition BaSO4
CAS 7727-43-7
Melting Point 1580
Density 4.25-4.5
Molecular Weight mol. wt. = 233.43
Refractive Index 1.636; 1.637; 1.648

Hazards and Safety

Nonpoisonous. Used in medical radiography because of its density and its water insolubility. Noncombustible.

International Chemical Safety Card

Additional Information

° R. Feller, "Barium Sulfate", Artists Pigments, Volume 1, R. Feller (ed.), Cambridge University Press: Cambridge, 1986.

Comparisons

Characteristics of Common White Pigments


Additional Images


Sources Checked for Data in Record

  • R. J. Gettens, G.L. Stout, Painting Materials, A Short Encyclopaedia, Dover Publications, New York, 1966 Comment: density = 4.36 and ref. index = 1.62 - 1.64
  • G.S.Brady, Materials Handbook, McGraw-Hill Book Co., New York, 1971 Comment: p. 83
  • Ralph Mayer, A Dictionary of Art Terms and Techniques, Harper and Row Publishers, New York, 1969 (also 1945 printing)
  • R. Newman, E. Farrell, 'House Paint Pigments', Paint in America , R. Moss ed., Preservation Press, New York City, 1994
  • Michael McCann, Artist Beware, Watson-Guptill Publications, New York City, 1979
  • Matt Roberts, Don Etherington, Bookbinding and the Conservation of Books: a Dictionary of Descriptive Terminology, U.S. Government Printing Office, Washington DC, 1982
  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • Susan E. Schur, Conservation Terminology: A review of Past & Current Nomenclature of Materials, Technology and Conservation, Spring (p.34-39); Summer (p.35-38); Fall (p.25-36), 1985
  • Van Nostrand's Scientific Encyclopedia, Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976
  • Random House, Webster's Encyclopedic Unabridged Dictionary of the English Language, Grammercy Book, New York, 1997
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: Entry # 1023
  • The American Heritage Dictionary or Encarta, via Microsoft Bookshelf 98, Microsoft Corp., 1998

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