Difference between revisions of "Calcium chloride"

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== Description ==
 
== Description ==
  
The anhydrous form of calcium chloride is very [[hygroscopic]]. It is used as a desiccant. Calcium chloride also exists as dihydrate and hexahydrate crystals. These crystalline forms are used in antifreeze solutions, fire extinguishers, fireproofing solutions, wood preservatives, as a gelling agent for [[starch]] size and to [[ice melter|melt snow and ice]] from roads. Calcium chloride was used to speed up the rate of cure in [[mortar%20%28masonry%29|mortar]], [[shotcrete]], and dry-mix [[concrete]] until 1973 when it was replaced by a non-chloride accelerator because it corroded [[steel]] reinforcements.
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The anhydrous form of calcium chloride is very [[hygroscopic]] and thus used as a [[desiccant]]. Calcium chloride also exists as dihydrate and hexahydrate crystals; these crystalline forms are used in antifreeze solutions, fire extinguishers, fireproofing solutions, wood preservatives, as a gelling agent for [[starch]] size and to [[ice melter|melt snow and ice]] from roads. Calcium chloride was used to speed up the rate of cure in [[mortar%20%28masonry%29|Mortar]], [[shotcrete]], and dry-mix [[concrete]] until 1973 when it was replaced by a non-chloride accelerator because it corroded [[steel]] reinforcements.  Very small amounts of calcium chloride are used in food preparation as a sequestrant, firming agent or to increase calcium content.
  
[[[SliderGallery rightalign|calcium chloride.jpg~Chemical structure]]]
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== Risks ==
  
== Other Properties ==
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* Contact may cause irritation
 +
* Reaction with water is exothermic 
 +
* Ingestion may cause burns
 +
* LabChem: [https://www.labchem.com/tools/msds/msds/75446.pdf MSDS]
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==Physical and Chemical Properties==
  
 
Soluble in water (with the evolution of heat). pH = 8 - 9
 
Soluble in water (with the evolution of heat). pH = 8 - 9
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|-
 
|-
 
! scope="row"| Melting Point
 
! scope="row"| Melting Point
| 772
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| 772 C
 
|-
 
|-
 
! scope="row"| Density
 
! scope="row"| Density
| 2.152
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| 2.152 g/ml
 
|-
 
|-
 
! scope="row"| Molecular Weight
 
! scope="row"| Molecular Weight
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|-
 
|-
 
! scope="row"| Boiling Point
 
! scope="row"| Boiling Point
| >1600
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| >1600 C
 
|}
 
|}
  
== Hazards and Safety ==
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==Resources and Citations==
 
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* Wikipedia: [https://en.wikipedia.org/wiki/Calcium_chloride Calcium chloride] Accessed July 2023
Contact may cause irritation.  [http://www.cdc.gov/niosh/ipcsneng/neng1184.html International Chemical Safety Card]
 
 
 
== Authority ==
 
 
 
 
* G.S.Brady, ''Materials Handbook'', McGraw-Hill Book Co., New York, 1971  Comment: p. 140
 
* G.S.Brady, ''Materials Handbook'', McGraw-Hill Book Co., New York, 1971  Comment: p. 140
 
 
* Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993
 
* Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993
 
 
* Michael McCann, ''Artist Beware'', Watson-Guptill Publications, New York City, 1979
 
* Michael McCann, ''Artist Beware'', Watson-Guptill Publications, New York City, 1979
 
 
* Book and Paper Group, ''Paper Conservation Catalog'', AIC, 1984, 1989
 
* Book and Paper Group, ''Paper Conservation Catalog'', AIC, 1984, 1989
 
 
* Thomas C. Jester (ed.), ''Twentieth-Century Building Materials'', McGraw-Hill Companies, Washington DC, 1995
 
* Thomas C. Jester (ed.), ''Twentieth-Century Building Materials'', McGraw-Hill Companies, Washington DC, 1995
 
 
* ''Van Nostrand's Scientific Encyclopedia'', Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976
 
* ''Van Nostrand's Scientific Encyclopedia'', Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976
 
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 1630
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 1630
  

Latest revision as of 12:26, 14 July 2023

Description

The anhydrous form of calcium chloride is very Hygroscopic and thus used as a Desiccant. Calcium chloride also exists as dihydrate and hexahydrate crystals; these crystalline forms are used in antifreeze solutions, fire extinguishers, fireproofing solutions, wood preservatives, as a gelling agent for Starch size and to melt snow and ice from roads. Calcium chloride was used to speed up the rate of cure in Mortar, Shotcrete, and dry-mix Concrete until 1973 when it was replaced by a non-chloride accelerator because it corroded Steel reinforcements. Very small amounts of calcium chloride are used in food preparation as a sequestrant, firming agent or to increase calcium content.

Risks

  • Contact may cause irritation
  • Reaction with water is exothermic
  • Ingestion may cause burns
  • LabChem: MSDS

Physical and Chemical Properties

Soluble in water (with the evolution of heat). pH = 8 - 9

Composition CaCl2
CAS 10043-52-4
Melting Point 772 C
Density 2.152 g/ml
Molecular Weight mol. wt. = 110.98
Boiling Point >1600 C

Resources and Citations

  • Wikipedia: Calcium chloride Accessed July 2023
  • G.S.Brady, Materials Handbook, McGraw-Hill Book Co., New York, 1971 Comment: p. 140
  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • Michael McCann, Artist Beware, Watson-Guptill Publications, New York City, 1979
  • Book and Paper Group, Paper Conservation Catalog, AIC, 1984, 1989
  • Thomas C. Jester (ed.), Twentieth-Century Building Materials, McGraw-Hill Companies, Washington DC, 1995
  • Van Nostrand's Scientific Encyclopedia, Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 1630