Difference between revisions of "Methyl ethyl ketone"

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== Description ==
 
== Description ==
  
A colorless liquid [http://cameo.mfa.org/materials/fullrecord.asp?name=solvent solvent] with an acetone-like odor. Methyl ethyl ketone, or MEK, is used as a solvent for [http://cameo.mfa.org/materials/fullrecord.asp?name=cellulose%20nitrate cellulose nitrate] lacquers, [http://cameo.mfa.org/materials/fullrecord.asp?name=vinyl%20resin vinyl] films, [http://cameo.mfa.org/materials/fullrecord.asp?name=acrylic%20resin acrylic] coatings, [http://cameo.mfa.org/materials/fullrecord.asp?name=ink inks], and [http://cameo.mfa.org/materials/fullrecord.asp?name=alkyd%20resin alkyd] ([http://cameo.mfa.org/materials/fullrecord.asp?name=Glyptal Glyptal]) resins. It is also used as a component in [http://cameo.mfa.org/materials/fullrecord.asp?name=paint%20remover paint removers] and dry cleaning fluids. MEK does not dissolve [http://cameo.mfa.org/materials/fullrecord.asp?name=cellulose%20acetate cellulose acetate] or most [http://cameo.mfa.org/materials/fullrecord.asp?name=wax waxes].
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A colorless liquid  
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[[solvent|solvent]] with an acetone-like odor. Methyl ethyl ketone, or MEK, is used as a solvent for  
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[[cellulose%20nitrate|cellulose nitrate]] lacquers,  
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[[vinyl%20resin|vinyl]] films,  
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[[acrylic%20resin|acrylic]] coatings,  
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[[ink|inks]], and  
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[[alkyd%20resin|alkyd]] (
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[[Glyptal|Glyptal]]) resins. It is also used as a component in  
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[[paint%20remover|paint removers]] and dry cleaning fluids. MEK does not dissolve  
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[[cellulose%20acetate|cellulose acetate]] or most  
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[[wax|waxes]].
  
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
  
 
2-butanone; MEK; ethyl methyl ketone; ethylmethyl ketone; 2-oxobutane; methyl acetone; methylethyl ketone
 
2-butanone; MEK; ethyl methyl ketone; ethylmethyl ketone; 2-oxobutane; methyl acetone; methylethyl ketone
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[[[SliderGallery rightalign|methyl ethyl ketone.jpg~Chemical structure]]]
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 +
==Risks ==
  
[[[SliderGallery rightalign|methyl ethyl ketone.jpg~Chemical structure]]]
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* Flammable.  Flash point = -9C  Dangerous fire risk.  Explosive in limits air 2-10%.
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* Toxic by inhalation. 
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* Skin contact causes dermatitis.
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* Ingestion causes vomiting and abdominal pain.
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* Flinn Scientific: [https://www.flinnsci.com/sds_511-methyl-ethyl-ketone/sds_511/ SDS]
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* EPA lists MEK as hazardous waste due to ignitability; concentrations over 10% must be disposed of appropriately
  
== Other Properties ==
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== Physical and Chemical Properties ==
  
 
Miscible with water, ethanol, ether, benzene and oils.
 
Miscible with water, ethanol, ether, benzene and oils.
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|-
 
|-
 
! scope="row"| Melting Point
 
! scope="row"| Melting Point
| -86.4
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| -86.4 C
 
|-
 
|-
 
! scope="row"| Density
 
! scope="row"| Density
| 0.805
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| 0.805 g/ml
 
|-
 
|-
 
! scope="row"| Molecular Weight
 
! scope="row"| Molecular Weight
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|-
 
|-
 
! scope="row"| Boiling Point
 
! scope="row"| Boiling Point
| 79.6
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| 79.6 C
 
|}
 
|}
 
== Hazards and Safety ==
 
 
Flammable.  Flash point = -9C  Dangerous fire risk.  Explosive in limits air 2-10%. Toxic by inhalation.  Skin contact causes dermatitis. Ingestion causes vomiting and abdominal pain.
 
 
LINK: [http://www.cdc.gov/niosh/ipcsneng/neng0179.html International Chemical Safety Card]
 
  
 
== Comparisons ==
 
== Comparisons ==
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[[media:download_file_135.pdf|Properties of Common Solvents]]
 
[[media:download_file_135.pdf|Properties of Common Solvents]]
  
 
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==Resources and Citations==
 
 
== Sources Checked for Data in Record ==
 
  
 
* R. J. Gettens, G.L. Stout, ''Painting Materials, A Short Encyclopaedia'', Dover Publications, New York, 1966  Comment: acts well on cellulose acetate
 
* R. J. Gettens, G.L. Stout, ''Painting Materials, A Short Encyclopaedia'', Dover Publications, New York, 1966  Comment: acts well on cellulose acetate

Latest revision as of 12:24, 17 April 2024

Description

A colorless liquid Solvent with an acetone-like odor. Methyl ethyl ketone, or MEK, is used as a solvent for Cellulose nitrate lacquers, vinyl films, acrylic coatings, inks, and alkyd ( Glyptal) resins. It is also used as a component in paint removers and dry cleaning fluids. MEK does not dissolve Cellulose acetate or most waxes.

Synonyms and Related Terms

2-butanone; MEK; ethyl methyl ketone; ethylmethyl ketone; 2-oxobutane; methyl acetone; methylethyl ketone

Chemical structure

Methyl ethyl ketone.jpg


Risks

  • Flammable. Flash point = -9C Dangerous fire risk. Explosive in limits air 2-10%.
  • Toxic by inhalation.
  • Skin contact causes dermatitis.
  • Ingestion causes vomiting and abdominal pain.
  • Flinn Scientific: SDS
  • EPA lists MEK as hazardous waste due to ignitability; concentrations over 10% must be disposed of appropriately

Physical and Chemical Properties

Miscible with water, ethanol, ether, benzene and oils.

Composition CH3COCH2CH3
CAS 78-93-3
Melting Point -86.4 C
Density 0.805 g/ml
Molecular Weight mol. wt.= 72.12
Refractive Index 1.379
Boiling Point 79.6 C

Comparisons

Properties of Common Solvents

Resources and Citations

  • R. J. Gettens, G.L. Stout, Painting Materials, A Short Encyclopaedia, Dover Publications, New York, 1966 Comment: acts well on cellulose acetate
  • Reed Kay, The Painter's Guide To Studio Methods and Materials, Prentice-Hall, Inc., Englewood Cliffs, NJ, 1983
  • Ralph Mayer, A Dictionary of Art Terms and Techniques, Harper and Row Publishers, New York, 1969 (also 1945 printing)
  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993 Comment: does not dissolve cellulose acetate and most waxes
  • Michael McCann, Artist Beware, Watson-Guptill Publications, New York City, 1979
  • Random House, Webster's Encyclopedic Unabridged Dictionary of the English Language, Grammercy Book, New York, 1997
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 6149; ref. index=1.379
  • The American Heritage Dictionary or Encarta, via Microsoft Bookshelf 98, Microsoft Corp., 1998
  • CRC Handbook of Chemistry and Physics, Robert Weast (ed.), CRC Press, Boca Raton, Florida, v. 61, 1980 Comment: ref. index=1.377