Difference between revisions of "Merbromin"

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== Description ==
 
== Description ==
  
An [http://cameo.mfa.org/materials/fullrecord.asp?name=iridescence iridescent] green crystalline compound composed of mercuric acetate dibromide fluorescein. Merbromin forms a red aqueous solution that [http://cameo.mfa.org/materials/fullrecord.asp?name=fluorescence fluoresces] a bright yellow green.  Since its discovery in 1919, merbromin was widely used as a germicide and antiseptic under the common brand name of Mercurochrome.  In 1990, the U.S. banned its sale due to potential of [http://cameo.mfa.org/materials/fullrecord.asp?name=mercury mercury] poisoning.  Merbromin forms red stains that can be removed by washing first with [http://cameo.mfa.org/materials/fullrecord.asp?name=potassium permanganate permanganate] solution and then with [http://cameo.mfa.org/materials/fullrecord.asp?name=oxalic acid oxalic acid] solution (Merck Index, 1996).
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An [[iridescence|iridescent]] green crystalline compound composed of mercuric acetate dibromide fluorescein. Merbromin forms a red aqueous solution that [[fluorescence|fluoresces]] a bright yellow green.  Since its discovery in 1919, merbromin was widely used as a germicide and antiseptic under the common brand name of Mercurochrome.  In 1990, the U.S. banned its sale due to potential of [[mercury|mercury]] poisoning.  Merbromin forms red stains that can be removed by washing first with [[potassium%20permanganate|permanganate]] solution and then with [[oxalic%20acid|oxalic acid]] solution (Merck Index, 1996).
 
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[[[SliderGallery rightalign|merbromin.jpg~Chemical structure]]]
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
  
 
Mercurochrome; Merbromine; 'Monkey blood'; Asceptichrome; Cinfacromin; Supercrome orto; sodium mercurescein; mercuric acetate dibromide fluorescein; dibromohydroxymercurifluorescein disodium salt; 2,7-disodiumdibromo-4-hydroxymercurifluoescein
 
Mercurochrome; Merbromine; 'Monkey blood'; Asceptichrome; Cinfacromin; Supercrome orto; sodium mercurescein; mercuric acetate dibromide fluorescein; dibromohydroxymercurifluorescein disodium salt; 2,7-disodiumdibromo-4-hydroxymercurifluoescein
  
[[[SliderGallery rightalign|merbromin.jpg~Chemical structure]]]
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== Risks ==
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* Toxic by ingestion and inhalation.
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* Contains mercury. 
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* Colors skin red.
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* Fisher Scientific: [https://fscimage.fishersci.com/msds/16795.htm MSDS]
  
== Other Properties ==
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== Physical and Chemical Properties ==
  
 
Soluble in water to form a carmine red solution. pH (0.5% solution) = 8.8   
 
Soluble in water to form a carmine red solution. pH (0.5% solution) = 8.8   
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== Hazards and Safety ==
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==Resources and Citations==
 
 
Toxic by ingestion and inhalation. Contains mercury.  Colors skin red.
 
 
 
Fisher Scientific: [https://fscimage.fishersci.com/msds/16795.htm MSDS]
 
 
 
== Authority ==
 
  
* Richard S. Lewis, Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993
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* Richard S. Lewis, ''Hawley's Condensed Chemical Dictionary'', Van Nostrand Reinhold, New York, 10th ed., 1993
  
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 5914
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983  Comment: entry 5914
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* ''The American Heritage Dictionary'' or ''Encarta'', via Microsoft Bookshelf 98, Microsoft Corp., 1998
 
* ''The American Heritage Dictionary'' or ''Encarta'', via Microsoft Bookshelf 98, Microsoft Corp., 1998
  
* Wikipedia, the free encyclopedia, at http://www.wikipedia.com  Comment: http://en.wikipedia.org/wiki/Merbromin (Accessed Jan. 6 2006)
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* Wikipedia: http://en.wikipedia.org/wiki/Merbromin (Accessed Jan. 6 2006)
  
  
  
 
[[Category:Materials database]]
 
[[Category:Materials database]]

Latest revision as of 12:25, 18 October 2022

Bottle of Mercurochrome

Description

An iridescent green crystalline compound composed of mercuric acetate dibromide fluorescein. Merbromin forms a red aqueous solution that fluoresces a bright yellow green. Since its discovery in 1919, merbromin was widely used as a germicide and antiseptic under the common brand name of Mercurochrome. In 1990, the U.S. banned its sale due to potential of Mercury poisoning. Merbromin forms red stains that can be removed by washing first with permanganate solution and then with Oxalic acid solution (Merck Index, 1996).

Chemical structure

Merbromin.jpg

Synonyms and Related Terms

Mercurochrome; Merbromine; 'Monkey blood'; Asceptichrome; Cinfacromin; Supercrome orto; sodium mercurescein; mercuric acetate dibromide fluorescein; dibromohydroxymercurifluorescein disodium salt; 2,7-disodiumdibromo-4-hydroxymercurifluoescein

Risks

  • Toxic by ingestion and inhalation.
  • Contains mercury.
  • Colors skin red.
  • Fisher Scientific: MSDS

Physical and Chemical Properties

Soluble in water to form a carmine red solution. pH (0.5% solution) = 8.8

Insoluble in ethanol, acetone, chloroform, ether.

Composition C20H8Br2HgNa2O6
CAS 129-16-8
Molecular Weight mol. wt. = 750.7

Resources and Citations

  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 5914
  • The American Heritage Dictionary or Encarta, via Microsoft Bookshelf 98, Microsoft Corp., 1998