Difference between revisions of "Ammonium chloride"

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== Description ==
 
== Description ==
  
Slightly hygroscopic white crystals historically used to separate [http://cameo.mfa.org/materials/fullrecord.asp?name=gold gold] from [http://cameo.mfa.org/materials/fullrecord.asp?name=silver silver] or [http://cameo.mfa.org/materials/fullrecord.asp?name=copper copper].  Ammonium chloride was known in ancient times where legend tells it was observed in the Temple of Zeus-Ammon in Egypt as it was scraped from the ceiling after camel dung was burned. Ammoniun chloride has also been used as a [http://cameo.mfa.org/materials/fullrecord.asp?name=mordant mordant], as a textile finishing agent to produce luster and as a tanning agent for [http://cameo.mfa.org/materials/fullrecord.asp?name=leather leather]. Currently, the most common uses for ammonium chloride are as a soldering flux for [http://cameo.mfa.org/materials/fullrecord.asp?name=iron iron], as a component in galvanizing solutions, as an electrolyte in dry cells and as a metal coloring agent.
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Slightly hygroscopic white crystals historically used to separate [[gold|gold]] from [[silver|silver]] or [[copper|copper]].  Ammonium chloride was known in ancient times where legend tells it was observed in the Temple of Zeus-Ammon in Egypt as it was scraped from the ceiling after camel dung was burned. Ammoniun chloride has also been used as a [[mordant|mordant]], as a textile finishing agent to produce luster and as a tanning agent for [[leather|leather]]. Currently, the most common uses for ammonium chloride are as a soldering flux for [[iron|iron]], as a component in galvanizing solutions, as an electrolyte in dry cells and as a metal coloring agent.
 
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[[[SliderGallery rightalign|ammonium chloride.jpg~Chemical structure]]]
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
  
 
sal ammonia; sal ammoniac; sal ammoniacum; ammonium muriate; salmiak (Ces.); chlorid amonný (Ces.); ammoniumklorid (Dan., Sven.); Ammoniumchlorid (Deut.); cloruro di ammonio (It.); salmiakzout (Ned.); chlorek amonu (Pol.); nashadir (Arab.); naosha (Chin.); nao sadar (India); salmiac; Amchlor; Darammon
 
sal ammonia; sal ammoniac; sal ammoniacum; ammonium muriate; salmiak (Ces.); chlorid amonný (Ces.); ammoniumklorid (Dan., Sven.); Ammoniumchlorid (Deut.); cloruro di ammonio (It.); salmiakzout (Ned.); chlorek amonu (Pol.); nashadir (Arab.); naosha (Chin.); nao sadar (India); salmiac; Amchlor; Darammon
  
[[[SliderGallery rightalign|ammonium chloride.jpg~Chemical structure]]]
 
  
== Other Properties ==
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== Risks ==
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* Fisher Scientific: [https://beta-static.fishersci.com/content/dam/fishersci/en_US/documents/programs/education/regulatory-documents/sds/chemicals/chemicals-a/S25168C.pdf SDS]
  
Soluble in water, methanol, ethanol. Insoluble in acetone, ether, ethyl acetate. Incompatible with alkalis and lead or silver salts.   
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== Physical and Chemical Properties ==
  
Crystals form aggregates with conchoidal fracture.
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* Soluble in water, methanol, ethanol. Insoluble in acetone, ether, ethyl acetate.
 +
* Incompatible with alkalis and lead or silver salts.   
 +
* Crystals form aggregates with conchoidal fracture.
  
 
{| class="wikitable"
 
{| class="wikitable"
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|-
 
|-
 
! scope="row"| Melting Point
 
! scope="row"| Melting Point
| 340-350 (sublimes)
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| 340-350 C (sublimes)
 
|-
 
|-
 
! scope="row"| Density
 
! scope="row"| Density
| 1.5274
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| 1.5274 g/ml
 
|-
 
|-
 
! scope="row"| Molecular Weight
 
! scope="row"| Molecular Weight
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|-
 
|-
 
! scope="row"| Boiling Point
 
! scope="row"| Boiling Point
| 520
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| 520 C
 
|}
 
|}
  
== Hazards and Safety ==
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==Resources and Citations==
 
 
[http://www.cdc.gov/niosh/ipcsneng/neng1051.html International Chemical Safety Card]
 
 
 
== Authority ==
 
  
 
* R. J. Gettens, G.L. Stout, ''Painting Materials, A Short Encyclopaedia'', Dover Publications, New York, 1966
 
* R. J. Gettens, G.L. Stout, ''Painting Materials, A Short Encyclopaedia'', Dover Publications, New York, 1966
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* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983
 
* ''The Merck Index'', Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983
  
* ''Encyclopedia Britannica'', http://www.britannica.com  Comment: "Ammonium chloride" Encyclopædia Britannica Premium Service. [Accessed 25 Jan. 2003].
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* ''Encyclopedia Britannica'', http://www.britannica.com  Comment: "Ammonium chloride" [Accessed 25 Jan. 2003].
  
 
* Random House, ''Webster's Encyclopedic Unabridged Dictionary of the English Language'', Grammercy Book, New York, 1997
 
* Random House, ''Webster's Encyclopedic Unabridged Dictionary of the English Language'', Grammercy Book, New York, 1997
Line 66: Line 64:
 
* ''The American Heritage Dictionary'' or ''Encarta'', via Microsoft Bookshelf 98, Microsoft Corp., 1998
 
* ''The American Heritage Dictionary'' or ''Encarta'', via Microsoft Bookshelf 98, Microsoft Corp., 1998
  
* Wikipedia, the free encyclopedia, at http://www.wikipedia.com  Comment: http://en.wikipedia.org/wiki/Ammonium_chloride (Accessed Mar. 20, 2006) -for non-English terms
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* Wikipedia: http://en.wikipedia.org/wiki/Ammonium_chloride (Accessed Mar. 20, 2006) -for non-English terms
  
 
* Michael McCann, ''Artist Beware'', Watson-Guptill Publications, New York City, 1979
 
* Michael McCann, ''Artist Beware'', Watson-Guptill Publications, New York City, 1979

Latest revision as of 12:47, 26 April 2022

Description

Slightly hygroscopic white crystals historically used to separate Gold from Silver or Copper. Ammonium chloride was known in ancient times where legend tells it was observed in the Temple of Zeus-Ammon in Egypt as it was scraped from the ceiling after camel dung was burned. Ammoniun chloride has also been used as a Mordant, as a textile finishing agent to produce luster and as a tanning agent for Leather. Currently, the most common uses for ammonium chloride are as a soldering flux for Iron, as a component in galvanizing solutions, as an electrolyte in dry cells and as a metal coloring agent.

Chemical structure

Ammonium chloride.jpg

Synonyms and Related Terms

sal ammonia; sal ammoniac; sal ammoniacum; ammonium muriate; salmiak (Ces.); chlorid amonný (Ces.); ammoniumklorid (Dan., Sven.); Ammoniumchlorid (Deut.); cloruro di ammonio (It.); salmiakzout (Ned.); chlorek amonu (Pol.); nashadir (Arab.); naosha (Chin.); nao sadar (India); salmiac; Amchlor; Darammon


Risks

  • Fisher Scientific: SDS

Physical and Chemical Properties

  • Soluble in water, methanol, ethanol. Insoluble in acetone, ether, ethyl acetate.
  • Incompatible with alkalis and lead or silver salts.
  • Crystals form aggregates with conchoidal fracture.
Composition NH4Cl
CAS 12125-02-9
Mohs Hardness 1.0 - 2.0
Melting Point 340-350 C (sublimes)
Density 1.5274 g/ml
Molecular Weight mol. wt. = 53.5
Refractive Index 1.639
Boiling Point 520 C

Resources and Citations

  • R. J. Gettens, G.L. Stout, Painting Materials, A Short Encyclopaedia, Dover Publications, New York, 1966
  • Dictionary of Building Preservation, Ward Bucher, ed., John Wiley & Sons, Inc., New York City, 1996
  • G.S.Brady, Materials Handbook, McGraw-Hill Book Co., New York, 1971 Comment: p. 58
  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • Van Nostrand's Scientific Encyclopedia, Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983
  • Random House, Webster's Encyclopedic Unabridged Dictionary of the English Language, Grammercy Book, New York, 1997
  • The American Heritage Dictionary or Encarta, via Microsoft Bookshelf 98, Microsoft Corp., 1998
  • Michael McCann, Artist Beware, Watson-Guptill Publications, New York City, 1979
  • Susan E. Schur, Conservation Terminology: A review of Past & Current Nomenclature of Materials, Technology and Conservation, Spring (p.34-39); Summer (p.35-38); Fall (p.25-36), 1985