Difference between revisions of "Lithol red"

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! Pigment number !! Manufacture !! Pigment name !! Manufacture CI number !! Comments  
 
! Pigment number !! Manufacture !! Pigment name !! Manufacture CI number !! Comments  
 
|-
 
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| PY013 || Sun || diarylide AAMX yellow_rs|| 275-1149 ||  
+
| PR49:1 || Magruder || barium lithol red|| rl1204-dc ||  
 
|-
 
|-
| PY014 || Sun || diarylide AAOT yellow|| 274-1744 || FTIR spectra appear the same for all PY014
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| PR49:2 || Magruder || calcium lithol red|| rl1082-dc ||  
 
|-
 
|-
| PY014 || Magruder || diarylide yellow AAoT t-p lumps|| ya1161-lu || FTIR spectra appear the same for all PY014
+
| PR49:2 || Magruder || calcium lithol red y_s|| rl1348-dc ||  
 
|-
 
|-
| PY014 || Magruder || diarylide yellow AAoT s_o || ya1283-dc || FTIR spectra appear the same for all PY014
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| PR49:1|| Sun || barium lithol red || 210-2400 ||  
 
|-
 
|-
| PY017 || Sun || diarylide AAOA yellow|| 275-0023 ||  
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| PR49:2  || Sun || calcium lithol red || 211-4620 ||  
 
|-
 
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| PO034 || Sun || diarylide tolyl orange || 282-0034 ||  
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| PR49:2  || Sun || calcium lithol maroon|| 211-4980 ||  
|-
 
| PY083 || Magruder || diarylide yellow || yr1300-dc || FTIR spectra are the same for Sun and Magruder PY083
 
|-
 
| PY083 || Sun || diarylide AADMC yellow|| 275-0570 || FTIR spectra are the same for Sun and Magruder PY083
 
 
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Revision as of 07:24, 29 January 2020

Description

[BASF] A trademark for a series of bright red, metallic salts of a synthetic Azo dye. First patented in 1899 by Paul Julius (BASF), Lithol reds are made by combining Tobias acid (2-naphthylamine-1-sulfonic acid) and beta-naphthol. Variations in colors are obtained by forming the salts with Sodium, Barium, Calcium, and Strontium cations. Lithol reds are inexpensive and widely used in printing inks, crayons, enamels, stationery, and industrial paints. They are also used as a colorants in some plastics. Lithol reds are not lightfast in sunlight and have only been used in student grade artists paints.

- Na salt: yellowish red, PR 49, CI 15630, water soluble 
- Ba salt: bluish pink, PR 49:1, CAS 1248-18-6
- Ca salt: bright red, PR 49:2, CAS 1103-38-4
- Sr salt: purplish red, PR 49:3, CAS 1103-39-5

Synonyms and Related Terms

Lithol toner; Pigment Red 49; CI 15630; 1-sulfo-beta-naphthalene-azo-beta-naphthol; Harrison Red

FTIR Ba (MFA)

PR049.1 sun barium lithol 210-4200.TIF

FTIR Ca red(MFA)

PR049.2 sun calcium lithol red 211-4620.TIF

FTIR Ca maroon(MFA)

PR049.2 sun calcium lithol maroon 211-4980.TIF

Comparisons

Pigment number Manufacture Pigment name Manufacture CI number Comments
PR49:1 Magruder barium lithol red rl1204-dc
PR49:2 Magruder calcium lithol red rl1082-dc
PR49:2 Magruder calcium lithol red y_s rl1348-dc
PR49:1 Sun barium lithol red 210-2400
PR49:2 Sun calcium lithol red 211-4620
PR49:2 Sun calcium lithol maroon 211-4980

Other Properties

Poor lightfastness

Composition C20H14N2O4S

Hazards and Safety

May cause allergic reactions. May be contaminated with cancer causing chemicals.

Additional Information

º H. A. L. Standeven, "The History and Manufacture of Lithol Red, A Pigment Used by Mark Rothko in his Seagram and Harvard Murals of the 1950s and 1960s" Tate Papers, Issue 10, 2008. Link

º B.Berrie, S.Q.Lomax, "Azo Pigments: Their History, Synthesis, Properties and Use in Artists' Materials" in Studies in the History of Art, No.57, National Gallery of Art, Washington DC, 1997.

Sources Checked for Data in Record

  • R. J. Gettens, G.L. Stout, Painting Materials, A Short Encyclopaedia, Dover Publications, New York, 1966
  • Ralph Mayer, A Dictionary of Art Terms and Techniques, Harper and Row Publishers, New York, 1969 (also 1945 printing)
  • B. Berrie, S.Q. Lomax, 'Azo Pigments: Their History, Synthesis, Properties and Use in Artists' Materials', Studies in the History of Art , National Gallery of Art, Washington DC, No. 57, 1997
  • Thomas Gregory, The Condensed Chemical Dictionary, Reinhold Publishing, New York, 3rd ed., 1942
  • Michael McCann, Artist Beware, Watson-Guptill Publications, New York City, 1979

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