Rhodamine B

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Rhodamine

Description

A strong, bright red Fluorescent dye. Rhodamine B is a Basic dye that was developed in 1887 by Ceresole. It is used as Textile and Paper dye, as a pigment, and as a staining reagent for the detection of fats and oils. Some oil modified materials such as alkyds and urethanes will also stain with rhodamine (Wolbers et al 1990). Rhodamine B has been used as a fluorescent colorant in inks (ballpoint, printing), wood stains, Distemper paints, and shoe polish.

rhodamine

Synonyms and Related Terms

Basic Violet 10; CI 45170; tetraethylrhodamine; D&C Red No. 19, Solvent Red 49; Pigment Violet 1 (phosphotungstomolybdic acid salt); Pigment Red 169 (copper ferrocyanide salt); Pigment Red 173 (aluminum salt); Rhodamine (Deut.); Rodamina B (Esp.); rodamina B (Port.); rhodamine B (Fr.);

FTIR mm0107-dc(MFA)

PV1 rhodamine b (magruder mm0107-dc).TIF

FTIR mm0122-dc(MFA

Pv1 rhodamine B (magruder mm0122-dc).TIF

FTIR mm1219-dc(MFA)

Pv1 rhodamine B (magruder mm1219-dc).TIF

Raman (MFA)

Rhodamine (Forbes MFA 44) copy.tif

SEM

F44sem.jpg

EDS

F44edsbw.jpg

Chemical structure

Rhodamine b.jpg

Comparisons

Pigment number Manufacture Pigment name Manufacture CI number Comments
PV001 Sun rhodamine B 221-0035
PV001 Magruder rhodamine B mm0107-dc
PV001 Magruder rhodamine B mm0122-dc
PV001 Magruder rhodamine B mm1219-dc

Other Properties

Green crystals or violet powder. Soluble in water, ethanol, polar solvents.

Maximum absorption wavelength = 545 nm.

Maximum emission wavelength = 625 nm.

Composition C28H31ClN2O3
CAS 81-88-9
Melting Point 210-211
Molecular Weight mol. wt. = 478.68

Hazards and Safety

Carcinogen. Mutagen.

Mallinckrodt Baker: MSDS

Additional Information

° R. Wolbers, N. Sterman and C. Stavroudis, "Notes for Workshop on New Methods in the Cleaning of Paintings", 1990, GCI, Los Angeles. ° Website for absorption/fluorescent spectra: http://www.omlc.ogi.edu/spectra/PhotochemCAD/html/rhodamineB.html

Additional Images


Sources Checked for Data in Record

  • Reed Kay, The Painter's Guide To Studio Methods and Materials, Prentice-Hall, Inc., Englewood Cliffs, NJ, 1983
  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • Richard C. Wolbers, Nanette T. Sterman, Chris Stavroudis, Notes for Workshop on New Methods in the Cleaning of Paintings, J.Paul Getty Trust, Los Angeles, 1990
  • Monona Rossol, The Artist's Complete Health and Safety Guide, Allworth Press, New York, 1994
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 8349
  • Website address 1 Comment: www.straw.com/sig/dyehist - discovered 1887
  • Aldrich Chemical Catalog Comment: p. 1299
  • Colour Index International online at www.colour-index.org

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