Difference between revisions of "Diphenylcarbazide"

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== Description ==
 
== Description ==
  
White crystalline powder used for the colorimetric detection of [http://cameo.mfa.org/materials/fullrecord.asp?name=chromium chromium] in metals, tanned [http://cameo.mfa.org/materials/fullrecord.asp?name=leather leather], and [http://cameo.mfa.org/materials/fullrecord.asp?name=pigments pigments] (Odegaard et al 2000). Diphenylcarbazide gives a dark blue-violet positive reaction. Other metals, such as [http://cameo.mfa.org/materials/fullrecord.asp?name=cadmium cadmium], [http://cameo.mfa.org/materials/fullrecord.asp?name=mercury mercury], [http://cameo.mfa.org/materials/fullrecord.asp?name=magnesium magnesium], [http://cameo.mfa.org/materials/fullrecord.asp?name=silver silver], [http://cameo.mfa.org/materials/fullrecord.asp?name=nickel nickel], [http://cameo.mfa.org/materials/fullrecord.asp?name=tin tin], and [http://cameo.mfa.org/materials/fullrecord.asp?name=aluminum aluminum] will also react with diphenylcarbazide.
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White crystalline powder used for the colorimetric detection of [[chromium]] in metals, tanned [[leather]], and [[pigment|pigments]] (Odegaard et al 2000). Diphenylcarbazide gives a dark blue-violet positive reaction. Other metals, such as [[cadmium]], [[mercury]], [[magnesium]], [[silver]], [[nickel]], [[tin]], and [[aluminum]] will also react with diphenylcarbazide.
  
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==

Revision as of 14:22, 14 January 2014

Description

White crystalline powder used for the colorimetric detection of Chromium in metals, tanned Leather, and pigments (Odegaard et al 2000). Diphenylcarbazide gives a dark blue-violet positive reaction. Other metals, such as Cadmium, Mercury, Magnesium, Silver, Nickel, Tin, and Aluminum will also react with diphenylcarbazide.

Synonyms and Related Terms

2,2'-diphenylcarbonic dihydrazide; 1,5-diphenylcarbazide; S-diphenylcarbazide; DPC

Chemical structure

Diphenylcarbazide.jpg


Other Properties

Slightly soluble in water. Soluble in hot alcohol, acetone, glacial acetic acid

Composition C33H14N4O
CAS 140-22-7
Melting Point 168-171
Molecular Weight mol. wt. = 242.27

Hazards and Safety

Degrades in light.

May be harmful by ingestion or inhalation. Contact may cause irritation.

Mallinckrodt Baker: MSDS

Additional Information

N.Odegaard, S.Carroll, W.Zimmt, Material Characterization Tests for Objects of Art and Archaeology Archetype Publications, London, 2000, p.44.

Authority

  • The Merck Index, Susan Budavari (ed.), Merck Research Labs, Whitehouse Station, NJ, 12th Edition, 1996 Comment: entry 3333
  • N.Odegaard, S.Carroll, W.Zimmt, Material Characterization Tests for Objects of Art and Archaeology, Archetype Publications, London, 2000

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