Phloroglucinol

From CAMEO
Jump to navigation Jump to search

Description

White to yellowish crystals that are used to detect the presence of mechanical wood pulp in paper. Phloroglucinol test solution contains Hydrochloric acid and ethanol. A drop placed on the paper will turn red when Lignin is present (detection limit is about 5%). Iron will react with phloroglucinol giving a purple product. Once the two-part solution is mixed, it has a shelf life of 2-3 months (TAPPI T401).

Synonyms and Related Terms

phloroglucinol dihydrate; 1,3,5-benzenetriol; 1,3,5-trihydroxybenzene; phloroglucine; phloroglucin stain

Chemical structure

Phloroglucinol.jpg


Risks

  • Decomposes in light; store in dark container.
  • Inhalation and skin contact may cause irritation.
  • ThermoFisher: SDS

Physical and Chemical Properties

  • Soluble in ethanol, pyridine, ether. Slightly soluble in water.
  • Detection limit is about 5% when used as a stain to detect mechanical wood pulp.
Composition C6H3(OH)3
CAS 108-73-6
Melting Point 212-218 C
Molecular Weight mol. wt.=126.11

Resources and Citations

  • AIC Book and Paper Catalog, 10. Spot Tests, page 12.
  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • Matt Roberts, Don Etherington, Bookbinding and the Conservation of Books: a Dictionary of Descriptive Terminology, U.S. Government Printing Office, Washington DC, 1982
  • Book and Paper Group, Paper Conservation Catalog, AIC, 1984, 1989
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 7482