Difference between revisions of "Triethanolamine"

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== Description ==
 
== Description ==
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[[[SliderGallery rightalign|triethanolamine.jpg~Chemical structure]]]
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A pale yellow, viscous liquid that lightly smells of [[ammonia%20%28anhydrous%29|ammonia]]. Triethanolamine is used as an [[emulsifier|emulsifier]] in [[nonionic%20detergent|nonionic detergents]], and as a [[solvent|solvent]] in dry cleaning. It dissolves dried paint films, [[fat|fats]], [[casein|casein]], [[shellac|shellac]], and [[wax|wax]]. Ethanolamines are [[hygroscopic|hygroscopic]] and are used as [[humectant|humectants]] to soften [[hide|hides]] and condition [[wool|wool]]. Ethanolamines are also used as corrosion inhibitors because they are an effective [[scavenger|scavenger]] for [[sulfur|sulfur]]-containing gases. Triethanolamine (TEA) is used in photographic developing baths to promote the formation of fine-grain structure. TEA is a strong base may be reacted with a non-water soluble organic materials, such as [[oleic%20acid|oleic acid]], to produce a water-soluble [[soap|soap]] for use as a cleaning agent, [[surfactant|surfactant]], and emulsifier. TEA soaps have been used to dissolve old, dried [[oil%20paint|oil paints]]. TEA is nonvolatile and highly reactive; it should be thoroughly removed from any surface after use.
  
A pale yellow, viscous liquid that lightly smells of [http://cameo.mfa.org/materials/fullrecord.asp?name=ammonia%20%28anhydrous%29 ammonia]. Triethanolamine is used as an [http://cameo.mfa.org/materials/fullrecord.asp?name=emulsifier emulsifier] in [http://cameo.mfa.org/materials/fullrecord.asp?name=nonionic%20detergent nonionic detergents], and as a [http://cameo.mfa.org/materials/fullrecord.asp?name=solvent solvent] in dry cleaning. It dissolves dried paint films, [http://cameo.mfa.org/materials/fullrecord.asp?name=fat fats], [http://cameo.mfa.org/materials/fullrecord.asp?name=casein casein], [http://cameo.mfa.org/materials/fullrecord.asp?name=shellac shellac], and [http://cameo.mfa.org/materials/fullrecord.asp?name=wax wax]. Ethanolamines are [http://cameo.mfa.org/materials/fullrecord.asp?name=hygroscopic hygroscopic] and are used as [http://cameo.mfa.org/materials/fullrecord.asp?name=humectant humectants] to soften [http://cameo.mfa.org/materials/fullrecord.asp?name=hide hides] and condition [http://cameo.mfa.org/materials/fullrecord.asp?name=wool wool]. Ethanolamines are also used as corrosion inhibitors because they are an effective [http://cameo.mfa.org/materials/fullrecord.asp?name=scavenger scavenger] for [http://cameo.mfa.org/materials/fullrecord.asp?name=sulfur sulfur]-containing gases. Triethanolamine (TEA) is used in photographic developing baths to promote the formation of fine-grain structure. TEA is a strong base may be reacted with a non-water soluble organic materials, such as [http://cameo.mfa.org/materials/fullrecord.asp?name=oleic%20acid oleic acid], to produce a water-soluble [http://cameo.mfa.org/materials/fullrecord.asp?name=soap soap] for use as a cleaning agent, [http://cameo.mfa.org/materials/fullrecord.asp?name=surfactant surfactant], and emulsifier. TEA soaps have been used to dissolve old, dried [http://cameo.mfa.org/materials/fullrecord.asp?name=oil%20paint oil paints]. TEA is nonvolatile and highly reactive; it should be thoroughly removed from any surface after use.
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See also [[monoethanolamine|monoethanolamine]], and [[diethanolamine|diethanolamine]].
 
 
See also [http://cameo.mfa.org/materials/fullrecord.asp?name=monoethanolamine monoethanolamine], and [http://cameo.mfa.org/materials/fullrecord.asp?name=diethanolamine diethanolamine].
 
  
 
== Synonyms and Related Terms ==
 
== Synonyms and Related Terms ==
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TEA; tri(2-hydroxyethyl)amine; 2,2,2-triethanolamine; 2,2',2"-nitrilotrisethanol; tris(hydroxyethyl)amine; triethylolamine; trolamine
 
TEA; tri(2-hydroxyethyl)amine; 2,2,2-triethanolamine; 2,2',2"-nitrilotrisethanol; tris(hydroxyethyl)amine; triethylolamine; trolamine
  
[[[SliderGallery rightalign|triethanolamine.jpg~Chemical structure]]]
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== Risks ==
  
== Other Properties ==
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* Combustible. Flash point = 179 C.
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* Skin irritant, strongly basic. 
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* Inhalation may be toxic.
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* Cisco: [http://www.ciscochem.com/assets/triethanolamine-sds.pdf SDS]
  
Soluble in water, ethanol, acetone. Slightly soluble in ether.
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==Physical and Chemical Properties==
  
Hygroscopic.  Turns brown with exposure to air.
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* Soluble in water, ethanol, acetone. Slightly soluble in ether.
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* Hygroscopic.  Turns brown with exposure to air.
  
 
{| class="wikitable"
 
{| class="wikitable"
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|-
 
|-
 
! scope="row"| Melting Point
 
! scope="row"| Melting Point
| 21.2-21.6
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| 21.2-21.6 C
 
|-
 
|-
 
! scope="row"| Density
 
! scope="row"| Density
| 1.124
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| 1.124 g/ml
 
|-
 
|-
 
! scope="row"| Molecular Weight
 
! scope="row"| Molecular Weight
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|-
 
|-
 
! scope="row"| Boiling Point
 
! scope="row"| Boiling Point
| 335.4 (dec)
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| 335.4 C (dec)
 
|}
 
|}
  
== Hazards and Safety ==
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==Resources and Citations==
 
 
Combustible. Flash point = 179 C.
 
 
 
Skin irritant, strongly basic.  Inhalation may be toxic.
 
 
 
LINK: [http://www.cdc.gov/niosh/ipcsneng/neng1034.html International Chemical Safety Card]
 
 
 
== Authority ==
 
  
 
* ''Van Nostrand's Scientific Encyclopedia'', Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976
 
* ''Van Nostrand's Scientific Encyclopedia'', Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976

Latest revision as of 13:11, 16 June 2022

Description

Chemical structure

Triethanolamine.jpg

A pale yellow, viscous liquid that lightly smells of ammonia. Triethanolamine is used as an Emulsifier in nonionic detergents, and as a Solvent in dry cleaning. It dissolves dried paint films, fats, Casein, Shellac, and Wax. Ethanolamines are Hygroscopic and are used as humectants to soften hides and condition Wool. Ethanolamines are also used as corrosion inhibitors because they are an effective Scavenger for Sulfur-containing gases. Triethanolamine (TEA) is used in photographic developing baths to promote the formation of fine-grain structure. TEA is a strong base may be reacted with a non-water soluble organic materials, such as Oleic acid, to produce a water-soluble Soap for use as a cleaning agent, Surfactant, and emulsifier. TEA soaps have been used to dissolve old, dried oil paints. TEA is nonvolatile and highly reactive; it should be thoroughly removed from any surface after use.

See also Monoethanolamine, and Diethanolamine.

Synonyms and Related Terms

TEA; tri(2-hydroxyethyl)amine; 2,2,2-triethanolamine; 2,2',2"-nitrilotrisethanol; tris(hydroxyethyl)amine; triethylolamine; trolamine

Risks

  • Combustible. Flash point = 179 C.
  • Skin irritant, strongly basic.
  • Inhalation may be toxic.
  • Cisco: SDS

Physical and Chemical Properties

  • Soluble in water, ethanol, acetone. Slightly soluble in ether.
  • Hygroscopic. Turns brown with exposure to air.
Composition N(CH2CH2OH)3
CAS 102-71-6
Melting Point 21.2-21.6 C
Density 1.124 g/ml
Molecular Weight mol. wt. = 149.19
Boiling Point 335.4 C (dec)

Resources and Citations

  • Van Nostrand's Scientific Encyclopedia, Douglas M. Considine (ed.), Van Nostrand Reinhold, New York, 1976
  • Random House, Webster's Encyclopedic Unabridged Dictionary of the English Language, Grammercy Book, New York, 1997
  • Richard S. Lewis, Hawley's Condensed Chemical Dictionary, Van Nostrand Reinhold, New York, 10th ed., 1993
  • The Merck Index, Martha Windholz (ed.), Merck Research Labs, Rahway NJ, 10th edition, 1983 Comment: entry 9798
  • R. J. Gettens, G.L. Stout, Painting Materials, A Short Encyclopaedia, Dover Publications, New York, 1966
  • Matt Roberts, Don Etherington, Bookbinding and the Conservation of Books: a Dictionary of Descriptive Terminology, U.S. Government Printing Office, Washington DC, 1982
  • Hermann Kuhn, Conservation and Restoration of Works of Art and Antiquities, Butterworths, London, 1986
  • Conservation Materials Ltd., Catalog