Iron gall ink

Herd of Goats
MFA# 59.1008

Description

Iron gall ink

A black ink predominantly used from the 9th century until it was replaced by synthetic inks in the late 19th century. Iron gall inks contain Ferrous sulfate and Gall extracts (gallotannic acid and gallic acid) in an aqueous solution of gum arabic. Gallotannic acid reacts with iron in solution to form iron gallotannate. The brown solution is used as an ink. As it dries on the paper or parchment, the ink oxidizes to a permanent deep blue-black color. Lampblack, Logwood (red), Indigo (blue), or later, Aniline black, colorants were sometimes added to the ink to provide an initial dark color. Over time, iron gall inks can interact with paper causing severe degradation. Citric acid, Oxalic acid, and Potassium oxalate have been mentioned as sequestering agents to remove iron gall inks, but any addition of an acid to degraded paper or parchment is not recommended. Calcium phytate has be used as a Chelating agent.

Synonyms and Related Terms

iron gallotannate; Eisengallustinte (Deut.); Gallustinte (Deut.); encre ferrogallique (Fr.); sidirogalliko melani (Gr.); inchiostro metallo gallico (It.); inchiostro di noce di galla (It.); ijzergallusinkt (Ned.); tinta ferrogálica (Port.); ferric tannate; iron tannate; acid ink; iron-gall ink; iron-gall nut ink

FTIR (MFA)

Physical and Chemical Properties

Iron-gallotannate is insoluble in water, ethanol, ether Some colored additives may be soluble in water and organic solvents.

Resources and Citations

• Reissland, Birgit and Frank Ligterink (2011) The Iron Gall Ink Website Maintained by the Cultural Heritage Agency of the Netherlands.
• The Ink Corrosion Website at http://www.knaw.nl/ecpa/ink/intro.html
• R. J. Gettens, G.L. Stout, Painting Materials, A Short Encyclopaedia, Dover Publications, New York, 1966
• Hermann Kuhn, Conservation and Restoration of Works of Art and Antiquities, Butterworths, London, 1986
• A Glossary of Paper Conservation Terms, Margaret Ellis (ed.), Conservation Center of the Institute of Fine Arts, New York City, 1998
• Matt Roberts, Don Etherington, Bookbinding and the Conservation of Books: a Dictionary of Descriptive Terminology, U.S. Government Printing Office, Washington DC, 1982
• Wikipedia: http://en.wikipedia.org/wiki/Iron_gall_ink (Accessed Jan. 25, 2006)
• AMOL reCollections Glossary - http://amol.org.au/recollections/7/i/htm
• Art and Architecture Thesaurus Online, http://www.getty.edu/research/tools/vocabulary/aat/, J. Paul Getty Trust, Los Angeles, 2000